Characterization of a major refractory component of marine dissolved organic matter   总被引：2，自引：0，他引：2  

Norbert Hertkorn  Ronald Benner  Philippe Schmitt-Kopplin  Karl Kaiser  John I. Hedges 《Geochimica et cosmochimica acta》2006,70(12):2990-3010

Refractory carboxyl-rich alicyclic molecules (CRAM) are characterized in marine dissolved organic matter (DOM) using nuclear magnetic resonance spectroscopy and ultrahigh resolution mass spectrometry. CRAM are distributed throughout the water column and are the most abundant components of deep ocean DOM ever characterized. CRAM are comprised of a complex mixture of carboxylated and fused alicyclic structures with a carboxyl-C:aliphatic-C ratio of 1:2 to 1:7. CRAM are expected to constitute a strong ligand for metal binding, and multiple coordination across cations could promote aggregation and marine gel formation thereby affecting CRAM reactivity and the bioavailability of nutrients and trace metals. It appears CRAM are ultimately derived from biomolecules with structural similarities to sterols and hopanoids. The occurrence of CRAM in freshwater and terrestrial environments seems likely, considering the global distribution of biomolecules and the similarities of biogeochemical processes among environments.  相似文献   

TRANSALP—deep crustal Vibroseis and explosive seismic profiling in the Eastern Alps     

Ewald Lüschen  Daniela Borrini  Helmut Gebrande  Bernd Lammerer  Karl Millahn  Franz Neubauer  Rinaldo Nicolich  TRANSALP Working Group   《Tectonophysics》2006,414(1-4):9

The TRANSALP consortium, comprising institutions from Italy, Austria and Germany, carried out deep seismic reflection measurements in the Eastern Alps between Munich and Venice in 1998, 1999 and 2001. In order to complement each other in resolution and depth range, the Vibroseis technique was combined with simultaneous explosive source measurements. Additionally, passive cross-line recording provided three-dimensional control and alternative north–south sections. Profits were obtained by the combination of the three methods in sectors or depths where one method alone was less successful.The TRANSALP sections clearly image a thin-skinned wedge of tectonic nappes at the northern Alpine front zone, unexpected graben or half-graben structures within the European basement, and, thick-skinned back-thrusting in the southern frontal zone beneath the Dolomite Mountains. A bi-vergent structure at crustal scale is directed from the Alpine axis to the external parts. The Tauern Window obviously forms the hanging wall ramp anticline above a southward dipping, deep reaching reflection pattern interpreted as a tectonic ramp along which the Penninic units of the Tauern Window have been up-thrusted.The upper crystalline crust appears generally transparent. The lower crust in the European domain is characterized by a 6–7 km thick laminated structure. On the Adriatic side the lower crust displays a much thicker or twofold reflective pattern. The crustal root at about 55 km depth is shifted around 50 km to the south with respect to the main Alpine crest.  相似文献   

U–Pb and Hf isotopic analysis of zircon in lower crustal xenoliths from the Navajo volcanic field: 1.4 Ga mafic magmatism and metamorphism beneath the Colorado Plateau     

James L. Crowley  Mark D. Schmitz  Samuel A. Bowring  Michael L. Williams  Karl E. Karlstrom 《Contributions to Mineralogy and Petrology》2006,151(3):313-330

Zircon from lower crustal xenoliths erupted in the Navajo volcanic field was analyzed for U–Pb and Lu–Hf isotopic compositions to characterize the lower crust beneath the Colorado Plateau and to determine whether it was affected by ∼1.4 Ga granitic magmatism and metamorphism that profoundly affected the exposed middle crust of southwestern Laurentia. Igneous zircon in felsic xenoliths crystallized at 1.73 and 1.65 Ga, and igneous zircon in mafic xenoliths crystallized at 1.43 Ga. Most igneous zircon has unradiogenic initial Hf isotopic compositions (ɛ_Hf=+4.1–+7.8) and 1.7–1.6 Ga depleted mantle model ages, consistent with 1.7–1.6 Ga felsic protoliths being derived from “juvenile” Proterozoic crust and 1.4 Ga mafic protoliths having interacted with older crust. Metamorphic zircon grew in four pulses between 1.42 and 1.36 Ga, at least one of which was at granulite facies. Significant variability within and between xenoliths in metamorphic zircon initial Hf isotopic compositions (ɛ_Hf=−0.7 to +13.6) indicates growth from different aged sources with diverse time-integrated Lu/Hf ratios. These results show a strong link between 1.4 Ga mafic magmatism and granulite facies metamorphism in the lower crust and granitic magmatism and metamorphism in the exposed middle crust.  相似文献   

Potential of High-Resolution Satellite Data in the Context of Vulnerability of Buildings   总被引：1，自引：2，他引：1  

Marina Mueller  Karl Segl  Uta Heiden  Hermann Kaufmann 《Natural Hazards》2006,38(1-2):247-258

High-resolution space-borne remote sensing data are investigated for their potential to extract relevant parameters for a vulnerability analysis of buildings in European countries. For an evaluation of large earthquake scenarios, the number of parameters in models for vulnerability is reduced to a minimum of relevant information such as the type of building (age, material, number of storeys) and the geological and spatial context. Building-related parameters can be derived from remote sensing data either directly (e.g. height) or indirectly based on the recognition of the urban structure type in which the buildings are located. With the potential of a fully- or semi-automatic inventory of the buildings and their parameters, high-resolution satellite data and techniques for their processing are a useful supporting tool for the assessment of vulnerability.  相似文献   

Seasonal and interannual variability of phytoplankton pigment in the Laccadive (Lakshadweep) Sea as observed by the Coastal Zone Color scanner     

Lisa Jade Lierheimer  Karl Banse 《Journal of Earth System Science》2002,111(2):163-185

Based on Coastal Zone Color Scanner data from November 1978 through December 1981, the seasonal cycle of phytoplankton pigment in the upper part of the euphotic zone is established for the offshore Laccadive Sea. Year-round, the pigment content is low and the seasonal range is small, following the pattern of the nutrient-poor Arabian Sea to the west. Apparently, indigenous phytoplankton blooms are absent. July and August, however, were poorly studied because of cloud cover. Interannual differences during the northeast monsoon and the spring intermonsoon periods are minor. The abundant phytoplankton caused by the upwelling off India during the southwest monsoon remains essentially restricted to the shelf, but there are occasional large, zonal outbreaks into the Laccadive Sea, as well as others advected to the south of India. Visual inspection of the raw CZCS scenes for June through November 1982–1985, with almost no data until August or even September, shows such outbreaks of pigment-rich water to be common. Inspection of monthly SeaWiFS images for 1997 through part of 2001 confirms the absence of indigenous phytoplankton blooms.  相似文献   

Reproductive cycles of Mytilus edulis L. on the west and east coasts of Iceland     

Gudrun G. Thorarinsdóttir  Karl Gunnarsson 《Polar research》2003,22(2):217-223

Studies evaluating the reproductive pattern of Mytilus edulis L. were conducted in western and eastern Iceland at two sites at about the same latitude but with different temperature regimes. Mussels were sampled once or sometimes twice a month during two years in Breidifjördur, western Iceland and one year at Mjoifjördur, eastern Iceland. Gonad development was monitored by microscopic observation of thin sections of the gonads. The initiation of gonad development was observed in January in Breidifjördur while in Mjoifjördur some of the animals started developing gonads in October, a month before spawning was over in the population. Spawning started in late June or July, peaked in August and continued until November at both sites. Nutrient reserve stores seemed to be limited and used for initiation of gonad development in winter but were not sufficient for maturation of the gonads. The main growth of the gonads occured in spring in conjunction with phytoplankton blooming and renewal of food resources.  相似文献   

Understanding Climatic Impacts, Vulnerabilities, and Adaptation in the United States: Building a Capacity for Assessment     

Edward A. Parson  Robert W. Corell  Eric J. Barron  Virginia Burkett  Anthony Janetos  Linda Joyce  Thomas R. Karl  Michael C. MacCracken  Jerry Melillo  M. Granger Morgan  David S. Schimel  Thomas Wilbanks 《Climatic change》2003,57(1-2):9-42

Based on the experience of the U.S. National Assessment, we propose a program of research and analysis to advance capability for assessment of climate impacts, vulnerabilities, and adaptation options. We identify specific priorities for scientific research on the responses of ecological and socioeconomic systems to climate and other stresses; for improvement in the climatic inputs to impact assessments; and for further development of assessment methods to improve their practical utility to decision-makers. Finally, we propose a new institutional model for assessment, based principally on regional efforts that integrate observations, research, data, applications, and assessment on climate and linked environmental-change issues. The proposed program will require effective collaboration between scientists, resource managers, and other stakeholders, all of whose expertise is needed to define and prioritize key regional issues, characterize relevant uncertainties, and assess potential responses. While both scientifically and organizationally challenging, such an integrated program holds the best promise of advancing our capacity to manage resources and the economy adaptively under a changing climate.  相似文献   

Ground Water Beneath Coastal Bays of the Delmarva Peninsula: Ages and Nutrients   总被引：2，自引：0，他引：2  

John F. Bratton  John Karl Böhlke  Frank T. Manheim  David E. Krantz 《Ground water》2004,42(7):1021-1034

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Dynamics of an active rock glacier (Ötztal Alps, Austria)     

Jana Berger  Karl Krainer  Wolfram Mostler 《Quaternary Research》2004,62(3):233-242

The rock glacier Innere Ölgrube, located in a small side valley of the Kauner Valley (Ötztal Alps, Austria), consists of two separate, tongue-shaped rock glaciers lying next to each other. Investigations indicate that both rock glaciers contain a core of massive ice. During winter, the temperature at the base of the snow cover (BTS) is significantly lower at the active rock glacier than on permafrost-free ground adjacent to the rock glacier. Discharge is characterized by strong seasonal and diurnal variations, and is strongly controlled by the local weather conditions. Water temperature of the rock glacier springs remains constantly low, mostly below 1°C during the whole melt season. The morphology of the rock glaciers and the presence of meltwater lakes in their rooting zones as well as the high surface flow velocities of >1 m/yr point to a glacial origin. The northern rock glacier, which is bounded by lateral moraines, evolved from the debris-covered tongue of a small glacier of the Little Ice Age with its last highstand around A.D. 1850. Due to the global warming in the following decades, the upper parts of the steep and debris-free ice glacier melted, whereas the debris-covered glacier tongue transformed into an active rock glacier. Due to this evolution and due to the downslope movement, the northern rock glacier, although still active, at present is cut off from its ice and debris supply. The southern rock glacier has developed approximately during the same period from a debris-covered cirque glacier at the foot of the Wannetspitze massif.  相似文献   

Characterizing the properties of dissolved organic matter isolated by XAD and C-18 solid phase extraction and ultrafiltration   总被引：1，自引：0，他引：1  

Sara B. Schwede-Thomas  Yu-Ping Chin  Karl J. Dria  Patrick Hatcher  Edith Kaiser  Barbara Sulzberger 《Aquatic Sciences - Research Across Boundaries》2005,67(1):61-71

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